Product ID:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE, ACC26370
MSDS Date:08/13/1996
FSC:6810
NIIN:00N077904
MSDS Number: CFHBB

FISHER SCIENTIFIC

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM;1250 STEL

PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE

RTECS: 9999999ZZ

AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF

RTECS: 9999999ZZ

SUBSTANCE CAUSES CARD SENSIT TO ENDOGENOUS

RTECS: 9999999ZZ

USE ADRENERGIC AGENTS SUCH AS EPINEPHRINE OR

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 43 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY
BE CONTRAINDICATED EXCEPT FOR LI FE-SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CFC'S . ACUTE:EYE:CONT PRDCES IRRIT,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:TEARING & BURNING PAIN. MAY CAUSE
CONJ. SKIN:MAY CAUSE IRRIT. PRLNG &/OR RPTD CONT MAY CAUSE DEFAT &
DERM. INGEST:INGEST OF LG AMTS MAY CAUSE GI IRRIT. EXPECTED TO BE
LOW HAZ. INHAL:INHAL OF HIGH CONCS MAY CAUSE CNS EFTS CHARACT BY
HDCH, DIZZ, UNCON & COMA. VAP REDUCES OXYG AVAIL FOR BRTHG. MAY
CAUSE (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, OCCAS
LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN:FLUSH W/PLENTY OF
SOAP & WATER FOR AT LST 15 MINS WHILE REMOVING CONTAM CLTHG &
SHOES. GET ME D AID IF IRRIT DEVELS/PERSISTS. INGEST:IF VICTIM IS
CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE
ANYTHING BY MOUTH TO UNCON PERS. GET MED AID. INHAL:REMOVE FROM
EXPOS TO FRESH (ING 3)

Flash Point:NONE
Extinguishing Media:FOR SMALL FIRES, USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE OR CHEMICAL FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT . VAPORS MAY BE FLAMMABLE IN VESSELS OF
ADEQUATE SIZE.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE FLUORIDES, CHLORIDES & PHOSGENE .

Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION SECTION. ABSORB
SPILL W/INERT MATERIAL, (E.G., DRY SAND OR EARTH), THEN PLACE INTO
CHEMICAL WASTE CONTAI NER. REMOVE ALL SOURCES OF IGNITION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONTACT W/SKIN & EYES. AVOID
INGEST & INHAL. KEEP FROM CONT W/OXIDIZING MATLS. KEEP AWAY FROM
METALS. DO NOT STORE IN ALUMINUM CONTAINERS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF CHLORIDES, FLUORIDES/PHOSGENE . USE W/ADEQ VENT. STORE IN
COOL, DRY , WELL-VENTED AREA AWAY FROM (SUPP DATA)

Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN 29
CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL
AIRBORNE LEVELS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT
W/SKIN.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID:SODIUM-POTASSIUM ALLOY, TITANIUM, ZINC, MAGNESIUM &
BERYLLIUM. OTHER PREC:INCOMPAT SUBSTANCES. IF YOU FEEL UNWELL, SEEK
MED ADVICE (SHOW LBL WHERE POSS). EYE PROT:FULL LGTH FSHLD . EFTS
OF OVEREXP:HEART DISTURBS, POSSIBLY LEADING TO CARDIAC ARREST &
DEATH. MAY CAUSE NARCOTIC EFTS. CHRONIC: (ING 2)

Boiling Pt:B.P. Text:188F,87C
Melt/Freeze Pt:M.P/F.P Text:55.8F,13.2C
Vapor Pres:273 @ 20C
Vapor Density:6
Spec Gravity:1.6
Evaporation Rate & Reference:0.45 (ACETONE=1)
Solubility in Water:0.028%
Appearance and Odor:COLORLESS LIQUID; SLIGHT ETHEREAL ODOR.

Stability Indicator/Materials to Avoid:YES
INCOMPAT W/ALKALI OR ALKALINE EARTH METALS SUCH AS SODIUM, POTASSIUM,
ALUMINUM, BARIUM, LITHIUM, SAMARIUM, (SUPP DATA)
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES,
METALS, STRONG OXIDIZERS.
Hazardous Decomposition Products:CHLORIDES, FLUORIDES . HYDROGEN
CHLORIDE, PHOSGENE, CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN
FLUORIDE.

Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT W/FEDERAL,
STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.